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Substrate-governed residual amine distribution prior to interfacial polymerization: a dissipative particle dynamics study
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DOI：10.1016/j.memsci.2026.125963.png)
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Abstract
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• DPD simulations reveal how substrates control pre-IP residual amine distribution. • Substrate hydrophilicity/hydrophobicity determines pore infiltration vs surface aggregation. • Substrate pore size, density and porosity jointly regulate aqueous phase distribution. • Four regimes identified: restriction, disorder, ordering and free-interface. • Residual amine distribution potentially influenced subsequent IP and PA morphology.