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Supramolecular assembly of a poly(ionic liquid) ABC triblock copolymer with monovalent halogen bond donors
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DOI：10.1039/d5py01102g.png)
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Abstract
En 中文
This study demonstrates the interplay between halogen bonds and pi-pi stacking in ionic block copolymers, which directs the formation of supramolecular assemblies with tunable nanoscale architectures. Using pentafluoroiodobenzene and nonafluoro-1-iodobutane as halogen bond donors, with chloride counter anions as halogen bond acceptors, the results reveal stoichiometry-dependent changes in self-assembly, confirmed by nuclear magnetic resonance, isothermal titration calorimetry, dynamic light scattering, and microscopic analyses.
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3.9
Papers:
624
Citations:
2.6W