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Surface Hydroxyl-Promoted Visible-Light Activation of Peroxymonosulfate by ZnAl-LDH for Water Purification: Mechanistic Insights and Ecological Assessment
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DOI:10.1016/j.envres.2026.125430.png)
Abstract
En 中文
• A hydroxyl-rich ZnAl-LDH was synthesized via facile pH-tuning, enabling precise control of surface active sites. • Surface hydroxyls serve dual roles in PMS adsorption and activation, driving a synergistic radical/nonradical pathway. • DFT and experiments reveal the electron-transfer mechanism and atomic-level PMS-catalyst interaction. • The system shows practical efficacy and high eco-safety in continuous flow and multispecies toxicity tests.
Journal
IF:
7.7
Papers:
2.0W
Citations:
9.0W
