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Synthesis and thermal degradation mechanism of phosphorus-containing fluorene-based copolyarylates
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DOI：10.1016/j.polymdegradstab.2026.112371.png)
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Abstract
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• A phosphorus- and fluorene-containing copolyarylate series was synthesized. • PPD improved solubility and lowered Tg while retaining high thermal stability. • PPD redistributed backbone-derived volatile pyrolysis products. • Phosphorus-rich residues became denser and more continuous.
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