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Synthesis of α-Fluorocyclopentenones by One-Pot Catalytic Acyl Migration and Nazarov Cyclization/Fluorination
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DOI：10.1002/asia.70711.png)
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Abstract
En 中文
In this study, we report a one-pot acyl migration and Nazarov cyclization/fluorination reaction by combining gold and copper catalysis, leading to the rapid construction of alpha-fluorocyclopentenones without the requirement of intermediate isolation. Moreover, preliminary results have been obtained for the catalytic enantioselective transformation. Notably, this reaction provides an efficient methodology for one-pot synthesis and fluorination reaction.
Keywords:
copper catalysis
electrophilic fluorination
gold catalysis
Nazarov cyclization
one-pot reaction
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3.3
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8.1K
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