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Tetraphenylethylene-substituted salen complexes of Cu(II), Zn(II), and Ni(II): structural, photophysical, electrochromic and electrofluorochromic properties
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DOI：10.1016/j.molliq.2026.129643.png)
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Abstract
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• TPE-salen Cu(II), Zn(II), and Ni(II) complexes were synthesized. • Metal-dependent ligand-centered redox behavior has been observed. • Spectroelectrochemistry reveals visible–NIR electrochromism. • Zn(II) system exhibits distinct electrofluorochromism.
Keywords:
TPE-salen complexes
metal-dependent redox behavior
electrochromism
electrofluorochromism
visible–NIR electrochromism
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