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The impact of anion mixing on Li+ coordination and transport properties in pyrrolidinium-based ionic liquid electrolytes
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DOI：10.1039/d6cp00353b.png)
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Abstract
En 中文
A series of pyrrolidinium-based ionic liquid electrolytes were investigated to explore the potential benefits of incorporating mixed anions, such as bis(fluorosulfonyl)imide and bis(trifluoromethylsulfonyl)imide used in this study. The effect of mixing anions on fundamental physicochemical properties was investigated, with particular emphasis on transport properties and lithium-ion coordination. More specifically, the electrolytes were systematically characterized in terms of phase behavior, density, viscosity, transport properties (ionic conductivity and self-diffusion), and intermolecular interactions. The results show that mixing anions modifies the nature of intermolecular interactions, which, in turn, alters the coordination of Li+ with its counterions. In the case of the (LiFSI)(0.2)(Pyr(14)TFSI)(0.8) sample, this resulted in improved thermal and transport properties, anticipating an improved performance in lithium-ion batteries.
Keywords:
PHYSICAL-PROPERTIES
ENERGY APPLICATIONS
PHASE-BEHAVIOR
TFSI
MIXTURES
DIFFUSION
LITFSI
FSI
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