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Ti4+ doping regulates cationic potential to construct a P2/O3 biphasic structure for synergistic optimization of cathode materials for sodium-ion batteries

delete2026-08-04
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PRE
AI
J
Jun Cong
S
Shaohua Luo *
S
Shengxue Yan
DOI:10.1016/j.mtchem.2026.103918delete
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Abstract

Abstract

En 中文
• Prime Novelty Statement • Ti4+ doping successfully induces the transformation of the material from a single P2 phase to a more stable P2/O3 biphasic coexistence structure. • The stabilization mechanism of Ti4+ doping is elucidated from a thermodynamic perspective using the total cationic potential and high-entropy design theories. • The optimized material achieves a ∼41% reduction in volume strain, significantly boosting structural reversibility and cycling stability.
Keywords:
Sodium-ion batteries
Cathode materials
Layered oxides
Bulk doping
P2/O3 biphasic coexistence

Journal

Materials Today Chemistry cover
Materials Today Chemistry
IF:
6.7
Papers:
3.6K
Citations:
1.4W

Organization

N
Northeastern University
Scholars:
2.3W
Papers: 1.5W
Citations: 3.0W
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