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Ultrafast Tea Polyphenol Surface Conditioning Creates a Zincophilic Interphase for Durable Zinc Anodes
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DOI：10.3390/nano16160992.png)
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Abstract
En 中文
The practical deployment of aqueous zinc-ion batteries (AZIBs) is critically limited by uneven Zn2+ flux, uncontrolled dendrite growth, and concurrent parasitic reactions—notably the hydrogen evolution reaction (HER) and anode corrosion—arising from interfacial and kinetic instability during repeated plating/stripping cycles. These issues originate at the zinc anode–electrolyte interface, underscoring the necessity of advanced interfacial engineering. Here, we report a surface-confined polyphenol-derived interphase formed on zinc foil through a 1 min dip treatment in a dilute aqueous solution of a commercial tea polyphenol (TP) mixture (0.02 M); after rinsing and drying, the modified electrode is cycled in a conventional electrolyte to which no TP is deliberately added. This interphase promotes more homogeneous nucleation behaviour through coordination between phenolic oxygen-containing moieties and Zn2+, improves electrolyte contact homogeneity and perturbs the local water structure to mitigate water-mediated parasitic reactions. The TP-derived surface modification creates a substantially altered interfacial charging environment (Cdl = 47.25 vs. 16.83 µF cm−2 for bare Zn) that facilitates more uniform zinc deposition. Symmetric cells with TP@Zn anodes demonstrated exceptional cycling stability exceeding 4000 h at 1 mA cm−2 and 1 mAh cm−2 (bare Zn fails within ~240 h under identical conditions), while TP@Zn//V2O5 full cells retained 56.2% capacity after 300 cycles at 0.5 A g−1 with a higher median discharge voltage than bare Zn cells, substantially outperforming the latter (31.1% retention). Density functional theory calculations using the selected cluster models yield a markedly more negative electronic interaction energy for Zn2+ with an EGCG model ligand (−10.97 eV) than with H2O (−4.49 eV), qualitatively supporting preferential coordination of Zn2+ by phenolic oxygen sites. This work presents a green, facile and potentially scalable interfacial regulation strategy and advances the understanding of natural polyphenols as pre-formed surface conditioners for highly reversible metal anodes.
Keywords:
aqueous zinc ion battery
zinc metal anode
tea polyphenol
surface modification
dendrite suppression
hydrogen evolution reaction
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