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Unraveling the mystery of polymorphic selection in the melt crystallization of piroxicam
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DOI：10.1016/j.molstruc.2026.145244.png)
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Abstract
En 中文
• The nucleation rates (forms III and VI) and growth rates (forms I-IV,VI-IX) of piroxicam polymorphs have been accurately measured. • Our kinetic measurements confirm that the polymorphic outcome in piroxicam’s melt crystallization is governed primarily by nucleation kinetics. • Specific hydrogen-bonding motifs and their stability predetermine the nucleation propensity in the melt.
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