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Unveiling the Single-Solvent Vacuum-Flash Process for High-Efficiency Perovskite Solar Cells

delete2025-11-17
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PRE
AI
H
Huanyu Zhang
Y
Yige Peng
Y
Yurou Zhang
Y
Yi Ji
Z
Zewu Feng
H
Hailong Huang
Y
Yanbo Wang
Y
Yansen Guo
C
Chenghao Ge
X
Xin Li
X
Xueqi Wu
Y
Yitong Liu
C
Chaopeng Huang
J
Jingsong Sun
张晓红 cover
张晓红 (Xiaohong Zhang)
彭军 cover
彭军 (Jun Peng)
DOI:10.1039/D5EE05421Ddelete
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Abstract

Abstract

En 中文
High-crystallinity perovskite films with low trap density are a prerequisite for realizing high-performance perovskite solar cells (PSCs). Here; we present a straightforward single-solvent vacuum-flash (SSVF) method for fabricating high-quality perovskite films using a simplified; single-solvent precursor system(e.g.; N; N-Dimethylformamide (DMF); dimethylacetamide (DMAC); and γ-valerolactone (GVL)). By creating a low temperature (LT) and vacuum environment for the precursor wet film; the SSVF method enables precise regulation of solvent evaporation dynamics; resulting in the formation of highly compact perovskite films with low trap densities. As a result; the PSCs fabricated via this method achieve a champion power conversion efficiency (PCE) of 26.93%; along with a certified PCE of 26.78% (certified steady-state efficiency of 26.39%). This performance ranks among the highest efficiencies ever reported for any vacuum-flash (VF)-based technique. Furthermore; owing to the enhanced phase stability of the perovskite film prepared via the SSVF method; the resulting PSC exhibits excellent operational durability; maintaining over 94% of its initial efficiency after 1000 hours of continuous operation.

Journal

Energy and Environmental Science cover
Energy and Environmental Science
IF:
30.8
Papers:
6.9K
Citations:
12.4W

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