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Visual kinetic analysis

delete2019-01-01
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OA
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C
Christian D.‐T. Nielsen
J
Jordi Burés *
DOI:10.1039/c8sc04698kdelete
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Abstract

Abstract

En 中文
Visual kinetic analyses extract meaningful mechanistic information from experimental data using the naked-eye comparison of appropriately modified progress reaction profiles. Basic kinetic information is obtained easily and quickly from just a few experiments. Therefore, these methods are valuable tools for all chemists working in process chemistry, synthesis or catalysis with an interest in mechanistic studies. This minireview describes the visual kinetic analyses developed in the last fifteen years and provides answers to the most common queries of new users. Furthermore, a video tutorial is attached detailing the implementation of both VTNA and RPKA.
Keywords:
CATALYST
MECHANISM
ELUCIDATION
AMINATION
ARYLATION
ALCOHOLS
ENZYME
AI Summary

AI Summary

Key information extracted from the uploaded paper, including a brief overview, abstract, background, key highlights, visual analysis, and future outlook.

Journal

Chemical Science cover
Chemical Science
IF:
7.4
Papers:
1.7W
Citations:
9.3W

Organization

I
Imperial College London
Scholars:
8.3W
Papers: 7.3W
Citations: 11.1W
U
University of Manchester
Scholars:
5.7W
Papers: 5.3W
Citations: 7.4W
Cited Papers

Cited Papers

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Reevaluation of the mechanism of the amination of aryl halides catalyzed by BINAP-ligated palladium complexes
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errShekhar, S; Ryberg, P; Hartwig, JF; Mathew, JS; Blackmond, DG; Strieter, ER; Buchwald, SL
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Investigations of Pd-catalyzed ArX coupling reactions informed by reaction progress kinetic analysis
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errMathew, Jinu S.; Klussmann, Martin; Iwamura, Hiroshi; Valera, Fernando; Futran, Alan; Emanuelsson, Emma A. C.; Blackmond, Donna G.
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On- and Off-Cycle Catalyst Cooperativity in Anion-Binding Catalysis
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errFord, David D.; Lehnherr, Dan; Kennedy, C. Rose; Jacobsen, Eric N.
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A Role for Pd(IV) in Catalytic Enantioselective C-H Functionalization with Monoprotected Amino Acid Ligands under Mild Conditions
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errPlata, R. Erik; Hall, David E.; Haines, Brandon E.; Musaev, Djamaladdin G.; Chu, Ling; Hickey, David P.; Sigman, Matthew S.; Yu, Jin-Quan; Blackmond, Donna G.
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