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Visualizing the Structural Solid-Liquid Transition at Colloidal Crystal/Fluid Interfaces
DOI:10.1002/adma.201004599.png)
Abstract
En 中文
The crystal/melt interface is central to the understanding of crystal nucleation and the morphological stability of crystal growth, but it is difficult to study experimentally. Micrometer-sized stimuli-dependent colloidal particles are assembled into large crystals using temperature fields. The structure of the colloidal crystal/melt interface is imaged directly in three dimensions. Interface reconstructions allow direct connection of the structure and interface free energy.
Keywords:
PHASE-BEHAVIOR
FREE-ENERGY
SUSPENSIONS
SYSTEMS
ANISOTROPY
GEOMETRY
SPHERES
MODEL
GLASS
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