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收藏A range of spin-crossover temperature T1/2 > 300 K results from out-of-sphere anion exchange in a series of ferrous materials based on the 4-(4-imidazolylmethyl)-2-(2-imidazolylmethy)imidazole (trim) ligand, [Fe(trim)2]X2 (X=F, Cl, Br, I):: Comparison of experimental results with those derived from density fuctional theory calculations
Lemercier, Gilles; Brefuel, Nicolas; Shova, Sergiu; Wolny, Juliusz A.; Dahan, Francoise; Verelst, Marc; Paulsen, Hauke; Trautwein, Alfred X.; Tuchagues, Jean-Pierre
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收藏A variety of spin-crossover behaviors depending on the counter anion:: Two-dimensional complexes constructed by NH•••Cl- hydrogen bonds, [FeIIH3LMe]Cl•X (X = PF6-, AsF6-, SbF6-, CF3SO3-; H3LMe = Tris[2-{[(2-methylimidazol-4-yl)methylidene]amino}ethyl]amine)
Yamada, Masahiro; Hagiwara, Hiroaki; Torigoe, Haruna; Matsumoto, Naohide; Kojima, Masaaki; Dahan, Francoise; Tuchagues, Jean-Pierre; re, Nazzano Re; Iijima, Seiichiro
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收藏A 2D layered spin crossover complex constructed by NH•••Cl- hydrogen bonds:: [FeIIH3LMe]]Cl•l3 (H3LMe = tris[2-(((2-methylimidazoyl-4-yl)methylidene)amino)ethyl]amine
Yamada, M; Fukumoto, E; Ooidemizu, M; Bréfuel, N; Matsumoto, N; Iijima, S; Kojima, M; Re, N; Dahan, F; Tuchagues, JP
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收藏Supramolecular spin-crossover iron complexes based on imidazole-imidazolate hydrogen bonds
Sunatsuki, Y; Ohta, H; Kojima, M; Ikuta, Y; Goto, Y; Matsumoto, N; Iijima, S; Akashi, H; Kaizaki, S; Dahan, F; Tuchagues, JP
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