Thomas B. Rauchfuss - Publications, H-index & Citations

Thomas B. Rauchfuss

School of Chemical Sciences

76H指数

920论文数

2.5W被引数

收录论文 204

发表时间

Synthesis of diiron subcluster [Fe2[(μ-SCH2)2NH](CN)2(CO)4]2− for artificial maturation of [FeFe]-hydrogenases 二铁次级簇[Fe2[(μ-SCH2)2NH](CN)2(CO)4]2−的合成及其在[FeFe]-氢化酶人工成熟中的应用

Nature Protocols

IF16

2026-08-13

PREAI

Xin Yu; Fang Wei; Thomas B. Rauchfuss

Biosynthesis of the Selenium-Substituted [FeFe]-Hydrogenases 硒取代[FeFe]-氢化酶的生物合成

Journal of the American Chemical Society

IF15.6

2026-06-16

OAAI

Xin Yu; Toby Woods; Yu Zhang; R. David Britt; Guodong Rao; Thomas B. Rauchfuss

[Fe2(μ-S2)(CN)2(CO)4]2–; [Fe2(μ-SH)2(CN)2(CO)4]2–; and [Fe2(μ-SH)(μ-SCH2NH2)(CN)2(CO)4]2– Related to the Biosynthesis of the [2Fe]H Site of the [FeFe]Hydrogenases [Fe2(μ-S2)(CN)2(CO)4]2–；[Fe2(μ-SH)2(CN)2(CO)4]2–；以及[Fe2(μ-SH)(μ-SCH2NH2)(CN)2(CO)4]2– 与[2Fe]H位点在[FeFe]氢化酶的生物合成相关

Inorganic Chemistry

IF4.7

2025-10-17

PREAI

Xin Yu; Toby Woods; Yu Zhang; Thomas B. Rauchfuss

Characterization of Complex-B ([Fe(κ3-cys)(CN)(CO)2]−); Biosynthetic Precursor to the [FeFe]-Hydrogenase Active Site; and Related Complexes 复杂物B ([Fe(κ3-cys)(CN)(CO)2]−) 的表征；[FeFe]-氢化酶活性位点的生物合成前体；及相关配合物

Journal of the American Chemical Society

IF15.6

2025-07-18

PREAI

Xin Yu; Toby J. Woods; Thomas B. Rauchfuss

The H-cluster of [FeFe] Hydrogenases: Its Enzymatic Synthesis and Parallel Inorganic Semisynthesis

ACCOUNTS OF CHEMICAL RESEARCH

IF17.7

2024-06-27

OAAI

Britt, R. David; Rauchfuss, Thomas B.; Rao, Guodong

Final Stages in the Biosynthesis of the [FeFe]-Hydrogenase Active Site

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

IF16.9

2024-04-18

OAAI

Yu, Xin; Rao, Guodong; Britt, R. David; Rauchfuss, Thomas B.

Synthesis, Spectroscopy, and Structure of [FeRu(μ-dithiolate)(CN)2(CO)4]2-

INORGANIC CHEMISTRY

IF4.7

2023-10-03

OAAI

Zhang, Yu; Wang, Ping; Xue, Shan; Woods, Toby; Guo, Yisong; Zampella, Giuseppe; Rauchfuss, Thomas B.; Arrigoni, Federica

Synthesis and Dynamics of Ferrous Polychalcogenides [Fe(Ex)(CN)2(CO)2]2- (E = S, Se, or Te)

INORGANIC CHEMISTRY

IF4.7

2022-05-13

OAAI

Zhang, Yu; Woods, Toby; Rauchfuss, Thomas B.

Organometallic Fe2(μ-SH)2(CO)4(CN)2 Cluster Allows the Biosynthesis of the [FeFe]-Hydrogenase with Only the HydF Maturase

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

IF15.6

2022-01-18

OAAI

Zhang, Yu; Tao, Lizhi; Woods, Toby J.; Britt, R. David; Rauchfuss, Thomas B.

Surprising Condensation Reactions of the Azadithiolate Cofactor

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

IF16.9

2021-08-18

OAAI

Zhang, Fanjun; Richers, Casseday P.; Woods, Toby J.; Rauchfuss, Thomas B.

Homoleptic Rhodium Pyridine Complexes for Catalytic Hydrogen Oxidation

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

IF15.6

2021-06-28

PREAI

Zhang, Yu; Woods, Toby J.; Rauchfuss, Thomas B.

Crystal Structure of the [FeFe]-Hydrogenase Maturase HydE Bound to Complex-B

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

IF15.6

2021-05-28

OAAI

Rohac, Roman; Martin, Lydie; Liu, Liang; Basu, Debashis; Tao, Lizhi; Britt, R. David; Rauchfuss, Thomas B.; Nicolet, Yvain

Vibrational Perturbation of the [FeFe] Hydrogenase H-Cluster Revealed by 13C2H-ADT Labeling

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

IF15.6

2021-05-27

OAAI

Pelmenschikov, Vladimir; Birrell, James A.; Gee, Leland B.; Richers, Casseday P.; Reijerse, Edward J.; Wang, Hongxin; Arragain, Simon; Mishra, Nakul; Yoda, Yoshitaka; Matsuura, Hiroaki; Li, Lei; Tamasaku, Kenji; Rauchfuss, Thomas B.; Lubitz, Wolfgang; Cramer, Stephen P.

Computational and Experimental Investigations of the Fe2(μ-S2)/Fe2(μ-S)2 Equilibrium

INORGANIC CHEMISTRY

IF4.7

2021-03-02

OAAI

Arrigoni, Federica; Zampella, Giuseppe; Zhang, Fanjun; Kagalwala, Husain N.; Li, Qian-Li; Woods, Toby J.; Rauchfuss, Thomas B.

Inhibition of [FeFe]-hydrogenase by formaldehyde: proposed mechanism and reactivity of FeFe alkyl complexes

CHEMICAL SCIENCE

IF7.4

2021-01-01

OAAI

Zhang, Fanjun; Woods, Toby J.; Zhu, Lingyang; Rauchfuss, Thomas B.

Biosynthesis of the [FeFe] hydrogenase H-cluster via a synthetic [Fe(ii)(CN)(CO)2(cysteinate)]- complex

DALTON TRANSACTIONS

IF3.3

2021-01-01

OAAI

Britt, R. David; Rauchfuss, Thomas B.

CO substitution by PPh3 in Fe2S2(CO)6 proceeds via a novel Fe2S intermediate

CHEMICAL COMMUNICATIONS

IF4.2

2021-01-01

OAAI

Zhang, Fanjun; Woods, Toby J.; Rauchfuss, Thomas B.; Arrigoni, Federica; Zampella, Giuseppe

Radical SAM Enzyme HydE Generates Adenosylated Fe(I) Intermediates En Route to the [FeFe]-Hydrogenase Catalytic H-Cluster

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

IF15.6

2020-05-21

OAAI

Tao, Lizhi; Pattenaude, Scott A.; Joshi, Sumedh; Begley, Tadhg P.; Rauchfuss, Thomas B.; Britt, R. David

Spectroscopic and Computational Evidence that [FeFe] Hydrogenases Operate Exclusively with CO-Bridged Intermediates

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

IF15.6

2019-12-10

OAAI

Birrell, James A.; Pelmenschikov, Vladimir; Mishra, Nakul; Wang, Hongxin; Yoda, Yoshitaka; Tamasaku, Kenji; Rauchfuss, Thomas B.; Cramer, Stephen P.; Lubitz, Wolfgang; DeBeer, Serena

The binuclear cluster of [FeFe] hydrogenase is formed with sulfur donated by cysteine of an [Fe(Cys)(CO)2(CN)] organometallic precursor

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

IF9.1

2019-09-30

OAAI

Rao, Guodong; Pattenaude, Scott A.; Alwan, Katherine; Blackburn, Ninian J.; Britt, R. David; Rauchfuss, Thomas B.

研究方向