袁相爱 (Xiang-Ai Yuan)

qufu normal university邮箱:xiang_aiyuan@qfnu.edu.cn

H指数:25

被引数:2,469

个人简介

"袁相爱，女，副教授；南京大学物理化学博士，主要研究方向为材料光学性质的理论研究，光催化反应及过渡金属催化反应机理研究。近几年在Nature Chemistry, Nature Communication, Angew, J.Mater.Chem,C, J. Phys. Chem. B., J. Phys. Chem. A., Org. Lett., Adv. Synth. Catal., Chem. Eur. J.等期刊发表论文四十多篇。主持国家自然科学基金青年基金1项，主持山东省自然科学基金一项，主持校级项目1项。参与多项国家和省级项目..."

教育背景

2012.09 – 2016.09
南京大学博士物理化学
2002.09 – 2005.07
南京师范大学硕士应用化学
1998.09 – 2002.06
曲阜师范大学学士化学工程与工艺

工作经历

暂无内容

荣誉奖项

暂无内容

Substituent-controlled highly regioselective hydroacylation of terminal alkynes catalyzed by rhodium complexes: A DFT study

取代基调控的末端炔烃高区域选择性水烷基化反应：钯配合物催化的密度泛函理论研究

Molecular Catalysis

IF4.9

2026-06-130

PRE

Anticancer evaluation of ferrocene-modified half-sandwich ruthenium(II) acylhydrazone complexes against A549 cell lines

铁羰基修饰的半夹心式钌(II)酰腙配合物对A549细胞系的抗癌评价

Journal of Inorganic Biochemistry

IF3.2

2026-05-030

PRE

Photoinduced Palladium Catalysis Enables Dynamic Kinetic Asymmetric Allylic Imidation

光诱导钯催化实现动态动力学不对称烯丙基咪唑化

Journal of the American Chemical Society

IF15.6

2026-04-010

PRE

Computational mechanistic insights into feeding sequence-controlled rhodium active catalysts for regio- and stereoselective hydrosilylation of terminal alkyne

计算机理研究揭示了控制末端炔烃区域和立体选择性硅氢化反应的钯活性催化剂的进料顺序。

Molecular Catalysis

IF4.9

2025-06-190

PRE

Effects of structurally varied fluorescent half-sandwich iridium(III) Schiff base complexes on A549 cell line

JOURNAL OF INORGANIC BIOCHEMISTRY

IF3.2

2025-02-013

PRE

Anticancer behavior of cyclometallated iridium(III)-tributyltin(IV) carboxylate schiff base complexes with aggregation-induced emission

JOURNAL OF INORGANIC BIOCHEMISTRY

IF3.2

2025-01-011

PRE

Design and anticancer behaviour of cationic/neutral half-sandwich iridium (III) imidazole-phenanthroline/phenanthrene complexes

阳离子/中性半夹心铱 (III) 咪唑-菲咯啉/菲配合物的设计和抗癌行为

JOURNAL OF INORGANIC BIOCHEMISTRY

IF3.2

2024-08-013

PRE

Ferrocene-modified half-sandwich iridium(III) and ruthenium(II) propionylhydrazone complexes and anticancer application

JOURNAL OF INORGANIC BIOCHEMISTRY

IF3.2

2024-08-013

PRE

Studies of Anticancer Activities In Vitro and In Vivo for Butyltin(IV)-Iridium(III) Imidazole-Phenanthroline Complexes with Aggregation-Induced Emission Properties

INORGANIC CHEMISTRY

IF4.7

2024-07-252

PRE

Differences in mechanisms between divalent and univalent copper complexes-catalyzed hydroacylation of terminal alkyne with aldehyde and amine

MOLECULAR CATALYSIS

IF4.9

2024-06-011

PRE

The anticancer application of half-sandwich iridium(III) ferrocene-thiosemicarbazide Schiff base complexes

DALTON TRANSACTIONS

IF3.3

2024-01-0112

PRE

Configurationally regulated half-sandwich iridium(III)-ferrocene heteronuclear metal complexes: Potential anticancer agents

JOURNAL OF INORGANIC BIOCHEMISTRY

IF3.2

2023-12-0114

PRE

Theoretical study on Pd(0)-catalyzed remote C(sp3)-H functionalization via 1,5-Pd migration

通过1，5-Pd迁移进行Pd(0) 催化的远程C(sp3)-H官能化的理论研究

MOLECULAR CATALYSIS

IF4.9

2023-07-014

PRE

Theoretical studies on the mechanisms and origins of substituent effects in CuBr-catalyzed three-component tandem reactions of terminal propargyl alcohols, aldehydes and amines

MOLECULAR CATALYSIS

IF4.9

2023-07-014

PRE

Kinetic Resolution of 2-Cinnamylpyrrolines Enabled by Photoexcited Chiral Copper Complex-Mediated Alkene E -* Z Isomerization

通过光激发手性铜络合物介导的烯烃E -* Z异构化实现2-肉桂基吡咯的动力学拆分

ACS CATALYSIS

IF13.1

2023-02-107

PRE

In Vitro and In Vivo Antitumor Assay of Mitochondrially Targeted Fluorescent Half-Sandwich Iridium(III) Pyridine Complexes

INORGANIC CHEMISTRY

IF4.7

2023-02-1016

PRE

Anticancer application of ferrocene appended configuration-regulated half-sandwich iridium(III) pyridine complexes

JOURNAL OF INORGANIC BIOCHEMISTRY

IF3.2

2022-12-0114

PRE

Insights into α-Alkynylation and α-Allenylation of Aldehydes under the Synergisitic Catalysis of Gold/Amine: A DFT Study

JOURNAL OF ORGANIC CHEMISTRY

IF3.6

2022-09-144

PRE

Distinctive Mechanistic Scenarios and Substituent Effects of Gold(I) versus Copper(I) Catalysis for Hydroacylation of Terminal Alkynes with Glyoxal Derivatives

JOURNAL OF ORGANIC CHEMISTRY

IF3.6

2022-08-197

PRE

Photoexcited Chiral Copper Complex-Mediated Alkene E → Z Isomerization Enables Kinetic Resolution

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

IF15.6

2022-06-0831

PRE

研究方向

欢迎感兴趣的本科生和研究生加入袁相爱课题组！！!发表学术论文氢化硅烷化反应机理有机金属催化机理理论研究CuBr催化三组分串联反应取代基效应的理论研究手性催化烯烃异构化Gold catalysisCopper catalysisHydroacylationAlkyne chemistry光激发手性铜配合物介导烯烃异构化动力学拆分锰催化二炔醇氢芳基化机理光氧化还原催化C-核苷类似物立体选择性合成Xu ShenCongcong Huang立体选择性合成光催化Liying MuWenjing FanXiang-Ai Yuan*Dan LiSiwei Bi*锰催化烯烃硅基化反应选择性氢芳基化金属-亚胺基卡宾化学与反应机理抗癌机制金属配合物构型控制铱(III) 2-苯基吡啶配合物的双重功能：转移抑制和溶酶体损伤Wang, D.He, Y.Dai, H.Huang, C.Yuan, X.-A.有机合成锰催化有机光氧化还原催化C-H键杂芳基化脱氧氘代反应无机化学抗肿瘤活性铱配合物光学性质研究多功能荧光PEG化氟化石墨烯靶向药物递送脱氧芳基化反应Ferrocenyl complexesLysosome-targeted imagingAnticancer agents有机半导体材料构象调控邻甲酚紫外吸收光谱溶剂效应有机催化亚胺逆水合硼化模块化合成金催化级联反应机理研究酰基转移酚加速效应金(I)催化偶联反应的化学选择性研究酰基转移机理耐热苯并嗪基聚芴的合成及其可逆温度敏感荧光有机金属化学环丙烷衍生物分子内与分子间氢键相互作用对邻甲酚水溶液红外光谱和紫外/可见吸收光谱的影响MD/TD-DFT与实验研究超分子光谱行为分子动力学模拟有机化学三氟甲基异喹啉合成