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A three-pole supramolecular switch
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DOI：10.1021/ja984341c.png)
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摘要
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A supramolecular system that switches reversibly, via three different states, through electrochemical adjustment of the guest properties of tetrathiafulvalene (TTF) has been developed. H-1 NMR, luminescence, and absorption spectroscopies, in conjunction with LSI mass spectrometry, X-ray crystallography, and cyclic/differential pulse voltammetries, established that the pi-electron-accepting (EA) tetrathiafulvalenium dication (TTF2+) binds strongly within the cavity of the pi-electron-donating (ED) macrocyclic polyether 1,5-dinaphtho[38]crown-10 (1/5DN38C10), generating a host-guest complex that is stabilized by, inter alia, pi-pi stacking interactions. Comparable techniques have also demonstrated that neutral tetrathiafulvalene (TTF(0)) acts as an ED guest when it complexes with the EA tetracationic cyclophane cyclobis(paraquat-p-phenylene) (CBPQT(4+)). On the other band, the tetrathiafulvalenium radical cation (TTF+.) is not bound by either of the hosts CBPQT(4+) or 1/5DN38C10. Electrochemical experiments revealed that the three-component mixture CBPQT(4+)-1/5DN38C10-TTF behaves as:a reversible three-pole supramolecular switch, since, depending on the potential range, TTF can be (1) free (in the TTF+. state), (2) included within the cavity of CBPQT(4+) (as TTF(0)), or (3) complexed with 1/5DN38C10 (in the TTF2+ state). The system's three-pole behavior has interesting implications in relation to the design of electrochromic displays and devices capable of controlling energy- or electron-transfer processes between selected components.
Keyword:
INDUCED MOLECULAR MOTIONS
AROMATIC CROWN-ETHERS
ELECTROCHEMICAL CONTROL
TETRATHIAFULVALENE
CHEMISTRY
SYSTEMS
COMPLEXATION
MACHINES
SENSORS
COPPER
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期刊
IF:
15.6
论文数:
20.0W
被引数:
60.2W
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