.png){kind=icon}
返回
Environmentally benign multiphase solid-liquid-gas catalysis
.png){kind=icon}
PRE
AI
DOI：10.1039/c9gc04063c.png)
.png){kind=icon}
原文求助.png){kind=icon}
分享.png){kind=icon}
收藏
摘要
En 中文
It is significant for the environment that molecular oxygen replaces conventional heavy metal-containing or toxic oxidants to participate in oxidation reactions. However, the involved gas-oil-solid multiphase catalytic reactions usually show low reaction efficiency due to the low solubility of gas in oil. Herein, an organic-inorganic hybrid with certain interfacial activity was synthesized by using an alkoxysilane covalent modified POM. Such a hybrid POM has surface activity and can be adsorbed at the gas-liquid interface, and allows direct contact between the gas, oil and catalyst at the interface. The performance of the foam system is superior to that of the conventional multiphase catalytic reaction at room temperature. In addition, no solvent was required for the reaction. The catalyst can be recovered by centrifugation after the reaction.
Keyword:
SELECTIVE OXIDATION
SUPERCRITICAL CO2
AEROBIC OXIDATION
MOLECULAR-OXYGEN
ALCOHOLS
METAL
ACID
TRANSFORMATION
HYDROGENATION
DERIVATIVES
AI总结
对已上传原文的论文进行重点信息的提取，主要内容包括：简要概述、研究摘要、背景介绍、关键亮点、图文解析、展望与总结。
期刊
IF:
9.2
论文数:
1.3W
被引数:
7.6W
机构
引用论文
Supported ruthenium catalyst for the heterogeneous oxidation of alcohols with molecular oxygen负载型钌催化剂用于醇与分子氧的多相氧化
OAAI
OAAI分享收藏Preparation and characterization of new ruthenium and osmium containing polyoxometalates, [M(DMSO)3Mo7O24]4- (M = Ru(II), Os(II)), and their use as catalysts for the aerobic oxidation of alcohols.png)
INORGANIC CHEMISTRY
INORGANIC CHEMISTRYIF4.7
PREAI
分享收藏Structural Transformation of Porous Polyoxometalate Frameworks and Highly Efficient Biomimetic Aerobic Oxidation of Aliphatic Alcohols多孔多金属氧酸盐框架的结构转变和脂肪醇的高效仿生好氧氧化ACS CATALYSIS
ACS CATALYSISIF13.1
PREAI
分享收藏The Polyoxovanadate-Based Carboxylate Derivative K6H[VV 17VIV 12(OH)4O60(OOC(CH2)4COO)8]•nH2O: Synthesis, Crystal Structure, and Catalysis for Oxidation of SulfidesINORGANIC CHEMISTRY
INORGANIC CHEMISTRYIF4.7
PREAI
分享收藏Liquid phase hydrogenation of maleic anhydride to 1,4-butanediol in a packed bubble column reactor
PREAI
分享收藏
查看更多内容