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Highly conductive, methanol resistant polyelectrolyte multilayers

delete2008-04-21
delete136
PRE
AI
A
Avni A. Argun
J
J. Nathan Ashcraft
P
Paula T. Hammond *
DOI:10.1002/adma.200703205delete
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摘要

摘要

En 中文
Highly conducting, methanol resistant thin films are fabricated using layer-by-layer (LBL) assembly. Pairing a sulfonated aromatic polyether with amine-based polycations yields LBL films with ionic conductivity values up to 3.5 x 10(-2) S cm(-1). Uniformly coating traditional fuel cell membranes with these LBL films (see figure) improves the power output of a direct methanol fuel cell by over 50%.
Keyword:
PROTON-EXCHANGE MEMBRANES
FUEL-CELL APPLICATIONS
LAYER POLYMER-FILMS
TRANSPORT-PROPERTIES
BLEND MEMBRANES
ELECTROLYTE
SULFONATION
PERMEATION
CROSSOVER
DMFCS
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期刊

Advanced Materials 封面图
Advanced Materials
IF:
26.8
论文数:
3.4W
被引数:
46.0W

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