Quantitative Surface-Enhanced Spectroscopy

Ryan D. Norton

doi:10.1146/annurev-physchem-082720-033751

2022-04-20

DOI：10.1146/annurev-physchem-082720-033751

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摘要

En 中文

Surface-enhanced Raman scattering (SERS), a powerful technique for trace molecular detection, depends on chemical and electromagnetic enhancements. While recent advances in instrumentation and substrate design have expanded the utility reproducibility, and quantitative capabilities of SERS, some challenges persist. In this review, advances in quantitative SERS detection are discussed as they relate to intermolecular interactions, surface selection rules, and target molecule solubility and accessibility. After a brief introduction to Raman scattering and SERS, impacts of surface selection rules and enhancement mechanisms are discussed as they relate to the observation of activation and deactivation of normal Raman modes in SERS. Next, experimental conditions that can be used to tune molecular affinity to and density near SERS substrates are summarized and considered while tuning these parameters is conveyed. Finally, successful examples of quantitative SERS detection are discussed, and future opportunities are outlined.

Keyword:

SERS

surface-enhanced Raman scattering

intermolecular interactions

quantitative detection

surface selection rules

期刊

Annual Review of Physical Chemistry

IF:

11.7

论文数:

1.5K

被引数:

8.9K

机构

University of Iowa

学者数:

2.8W

论文数: 2.3W

被引数: 600

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