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Route-selective enzymatic synthesis and structural elucidation of monooctanoylgalloylglycerols as amphiphilic phenolic structured lipids
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DOI：10.1016/j.crfs.2026.101527.png)
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Abstract
En 中文
• Efficient CALB-catalyzed synthesis of MOGGs via two-step esterification. • Optimized conditions produced 62.7% MOGG yield with controlled DOGG formation. • Qualitative docking supported comparison of substrate accommodation in CALB. • Medium-chain fatty acids showed superior acylation efficiency toward GG. • Sequential solvent-free synthesis without intermediate GG purification.
Keywords:
Monooctanoylgalloylglycerols
Lipase-catalyzed direct esterification
Galloyl structured lipids
Monoacylation selectivity
Structure elucidation
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