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Synthesis of 3-deaza-3-nitro-2′-deoxyadenosine
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DOI：10.1016/j.bmc.2005.10.040.png)
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Abstract
En 中文
Photoactivable deoxyadenosine mimic, 3-deaza-3-nitro-2'-deoxyadetiosine (2), was prepared using two different synthetic routes. The first route involved base catalyzed glycosylation of 3-deaza-3-nitroadenine, which was prepared by regioselective nitration of 3-deazaadenine. In the second route, the convertible nucleoside 6-O-(2,4,6-trimethylphenyl)-3-deaza-2'-deoxyadenosine (28) was used to introduce 6-NH2 group in the last step. (c) 2005 Elsevier Ltd. All rights reserved.
Keywords:
synthesis
photoactivable nucleoside
nitro compound
Journal
B
IF:
3
Papers:
1.7W
Citations:
2.7W
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