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Two-dimensional-materials-based transistors using hexagonal boron nitride dielectrics and metal gate electrodes with high cohesive energy

delete2024-08-26
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PRE
AI
Y
Yaqing Shen
K
Kaichen Zhu
Y
Yiping Xiao
D
Dominic Waldhoer
A
Abdulrahman H. Basher
T
Theresia Knobloch
S
Sebastián Pazos
X
Xianhu Liang
W
Wenwen Zheng
Y
Yue Yuan
J
J.B. Roldán
U
Udo Schwingenschlögl
田禾 (He Tian)
H
Huaqiang Wu
T
Thomas F. Schranghamer
N
Nicholas Trainor
J
Joan M. Redwing
S
Saptarshi Das
T
Tibor Grasser
M
Mario Lanza *
DOI:10.1038/s41928-024-01233-wdelete
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Abstract

Abstract

En 中文
Two-dimensional (2D) semiconductors could potentially be used as channel materials in commercial field-effect transistors. However, the interface between 2D semiconductors and most gate dielectrics contains traps that degrade performance. Layered hexagonal boron nitride (h-BN) can form a defect-free interface with 2D semiconductors, but when prepared by industry-compatible methods-such as chemical vapour deposition (CVD)-the presence of native defects increases leakage current and reduces dielectric strength. Here we show that metal gate electrodes with a high cohesive energy-platinum and tungsten-can allow CVD-grown layered h-BN to be used as a gate dielectric in transistors. The electrodes can reduce the current across CVD-grown h-BN by a factor of around 500 compared to similar devices with gold electrodes and can provide a high dielectric strength of at least 25 MV cm-1. We examine the behaviour statistically across 867 devices, which includes a microchip based on complementary metal-oxide-semiconductor technology. Metal gate electrodes with a high cohesive energy-platinum and tungsten-can be used to mitigate leakage currents and premature dielectric breakdown across chemical vapour deposition-grown multilayer hexagonal boron nitride, allowing the material to be used as a gate dielectric in two-dimensional-materials-based transistors.
Keywords:
FIELD
RESISTANCE
FILMS
MOS2

Journal

Nature Electronics cover
Nature Electronics
IF:
40.9
Papers:
1.7K
Citations:
2.1W

Organization

K
king abdullah university of science & technology
Scholars:
1.3W
Papers: 1.3W
Citations: 32
T
tsinghua university
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11.6W
Papers: 9.9W
Citations: 137
P
Pennsylvania State University
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3.0W
Papers: 2.6W
Citations: 7.2W
P
pennsylvania commonwealth system of higher education (pcshe)
Scholars:
12.8W
Papers: 11.7W
Citations: 177
T
Technische Universitat Wien
Scholars:
1.3W
Papers: 1.1W
Citations: 21
S
soochow university - china
Scholars:
5.1W
Papers: 3.5W
Citations: 82
U
University of Granada
Scholars:
2.2W
Papers: 1.9W
Citations: 24
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